Nhc-ni(ii)-catalyzed cyclopropene-isocyanide [5⠋+⠋1] benzannulation

HIGHLIGHTS

  • who: Jian-Qiang Huang from the Southern University have published the paper: NHC-Ni(II)-catalyzed cyclopropene-isocyanide [5u280b+u280b1] benzannulation, in the Journal: NATURE COMMUNICATIONS NATURE COMMUNICATIONS
  • what: In this work, instead of developing more practical imidoyl-M generation methods, the authors explore an alternate strategy that focuses on a formal addition of those two substrates in the absence of an a d 1= CNR R C OH R h Cat. The authors show a catalytic intermolecular isocyanide-cyclopropene benzannulation by NHC/NiBr2DME/NaBARF (1:1:2)29-36. This work has revealed several . . .

     

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