HIGHLIGHTS
- who: Weihao Chen from the (UNIVERSITY) have published the article: (NHC)Pd(II) hydride-catalyzed dehydroaromatization by olefin chain-walking isomerization and transfer-dehydrogenation, in the Journal: (JOURNAL) of 26/02/2022
- what: The authors show that Pd-H in the presence of an N-heterocyclic carbene ligand and an alkene regulator enables transfer-dehydroaromatization, avoiding the homo-disproportionation pathway. The authors provide a strategy to synthesize (hetero)aromatic compounds via chemoselective dehydrogenation of cyclic alkenes over ketones and the dehydrogenative Diels-Alder reaction of a cyclic enamine. The analysis presented above shows that the . . .
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