Non-aromatic 1,3-disilapyrroles: a class of stable organosilicon-based triplet diradicals

HIGHLIGHTS

  • who: Posted Date October and colleagues from the Xiamen University have published the article: Non-aromatic 1,3-Disilapyrroles: a class of stable organosilicon-based triplet diradicals, in the Journal: (JOURNAL)
  • what: The first 1,3-disilapyrroles 2H, t2H, 2F, and t2F, representing unprecedented isolable organosiliconbased triplet diradicals, have been synthesized and isolated from the reactions of the corresponding bis(silylenyl)anilines 1 and t1 with acetylene derivatives.

SUMMARY

    The control of electronic states is of paramount importance for tuning reactivity and properties of matter in chemistry, biology and the material . . .

     

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