Nonlinear electrophoresis of a highly charged particle by incorporating electrostatic correlations and ion steric interactions for a finite debye length

HIGHLIGHTS

• What: The authors determine the local viscosity μe scaled by μw as a function of local volume fraction (χ ) of finite-sized ions by the Batchelor-Green expression: (Batchelor and amp; Green 1972) μe (χ )=1 + 2.5χ + 5.2χ 2. The authors show in the subsequent section that the computed mobility μE based on the numerical simulation of the MNPC model for κa 1 is in excellent agreement with μHS governed by_(4.19) for a lower range of σ * and it exhibits mobility reversal for trivalent electrolytes. Model the authors have derived the corresponding Smoluchowski limit of the . . .
  

   

  

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