HIGHLIGHTS
SUMMARY
Electrochemistry is a powerful tool to study organic reactivity for the characterization of molecular properties as well as electrochemically driven synthesis. Abbreviations shown in Scheme 1 correspond to 1-bromo-2methylnaphthalene, 1-bromo-2-methylnaphthalene radical anion, 2-methylnaphthalene 1-bromo-2-methylnaphthalene radical anion, 2-methylnaphthalene radical, (R)-1,10 0 0 0 0 radical, (R)-1,1′-binaphthalene, (4′) (S)-1,1′-binaphthalene, 2,2′-dimethyl. A complete rotation cor(DRC) were performed starting from different equilibrium structures of the PES, such as responding to the conversion of the enantiomer R into . . .
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