HIGHLIGHTS
- who: Taiga Kodo from the Graduate School Kanazawa University, Kakuma-machi, Kanazawa, Japan have published the paper: Organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover, in the Journal: NATURE COMMUNICATIONS NATURE COMMUNICATIONS of 13/01/2022
- what: The authors report an organophotoredox-catalyzed decarboxylative semipinacol rearrangement of u03b2-hydroxyesters via RPC (Fig 1, bottom).
SUMMARY
The reported methods have mainly relied on ionic approaches using strong acids or bases as mediators, which limits the coexistable functional_groups and substrate structures (Fig 1, left top). The reaction design of semipinacol rearrangement via RPC . . .
If you want to have access to all the content you need to log in!
Thanks :)
If you don't have an account, you can create one here.