Ortho-f,f-dpephos : synthesis and coordination chemistry in rhodium and gold complexes, and comparison with dpephos

HIGHLIGHTS

• who: Race and collaborators from the (UNIVERSITY) have published the research: Ortho-F,F-DPEphos : Synthesis and Coordination Chemistry in Rhodium and Gold Complexes, and Comparison with DPEphos, in the Journal: (JOURNAL)
• what: We have highlighted the impact of ortho-fluorine substitution in organometallic chemistry through the control of aurophilic interactions in Au2Cl2(o-R,R-DPEphos) complexes (R=H or F) and the different hydrogenation products of common SchrockOsborn precatalysts.
• future: More detailed computational studies are needed to reconcile these chemical shift differences with the observed structure.

SUMMARY

 



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