Pentacobalt(ii) divanadium(iii) tetrakis(diphosphate), co5v2(p2o7)4

HIGHLIGHTS

• who: Å and collaborators from the Institut, Bonn, Germany have published the research: Pentacobalt(II) divanadium(III) tetrakis(diphosphate), Co5V2(P2O7)4, in the Journal: (JOURNAL) of 15/03/2013

SUMMARY

Co5V2(P2O7)4 was crystallized by chemical vapour transport using HCl as transport agent. Its crystal_structure is isotypic to that of FeII5FeIII2(P2O7)4 and can be regarded as a member of the thortveitite structure family with corrugated layers of metal-oxygen polyhedra extending parallel to. Significant occupational disorder between cobalt(II) and vanadium(III) is observed. Four of the five cation . . .

 



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