Perfluoroaryl zinc catalysts active in cyclohexene oxide homopolymerization and alternating copolymerization with carbon dioxide

HIGHLIGHTS

  • who: Yuri C. A. Sokolovicz and colleagues from the Department of Chemistry and Biology, University of Salerno, Fisciano, Italy have published the research work: Perfluoroaryl Zinc Catalysts Active in Cyclohexene Oxide Homopolymerization and Alternating Copolymerization with Carbon Dioxide, in the Journal: Catalysts 2022, 970 of /2022/
  • what: The strong Lewis acid catalyst Zn(C6 F5 )2 (toluene) (1) efficiently catalyses the homopolymerization of CHO, leading to PCHO with a remarkable TOF of 4200 min-1 via AMM.
  • how: The copolymer samples obtained at higher CO2 pressure the 13 main results are discussed in . . .

     

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