Photo-induced halogen-atom transfer: generation of halide radicals for selective hydrohalogenation reactions

HIGHLIGHTS

  • who: Lilian Geniller and collaborators from the (UNIVERSITY) have published the article: Photo-Induced Halogen-Atom Transfer: Generation of Halide Radicals for Selective Hydrohalogenation Reactions, in the Journal: (JOURNAL)
  • how: For reaching this goal the authors considered the use of abundant and inexpensive 12-dihaloethanes (DXE).

SUMMARY

    Contrary to radical transformations involving XAT reactivity, which exploit stable carbon radicals, this unique approach uses 1,2-dihaloethanes for the generation of unstable carbon radicals by XAT. Research Article doi.org/10.1002/chem. toxic reaction conditions.[8] However, the reported photomediated XATs . . .

     

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