Rapid access to polycyclic n-heteroarenes from unactivated, simple azines via a base-promoted minisci-type annulation

HIGHLIGHTS

• who: Jae Bin Lee from the Ulsan National Institute of Science and Technology (UNIST), UNIST-gil, Ulsan, Republic of KoreaYonsei University have published the article: Rapid access to polycyclic N-heteroarenes from unactivated, simple azines via a base-promoted Minisci-type annulation, in the Journal: NATURE COMMUNICATIONS NATURE COMMUNICATIONS of 11/04/2022
• what: The authors show the direct transformation of simple and electron-deficient heteroarenes to N-PACs based on an APEX reaction that is initiated by electron transfer and proceeds through radical relay events akin to the Minisci reaction (Fig 1b). The authors . . .
  

   

  

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