Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site electrophilic/cationic organo-zirconium catalyst

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  • who: Alexander H. Mason from the (UNIVERSITY) have published the Article: Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site electrophilic/cationic organo-zirconium catalyst, in the Journal: (JOURNAL)
  • what: The authors report that ZrNp4 chemisorption on sulfated alumina (Hammett acidity, H0 u2248 -14.6)24 yields AlS/ZrNp2, characterized by solid-state nuclear magnetic_resonance (NMR) spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray absorption near-edge structure (XANES), extended X-ray absorption fine structure (EXAFS), and density-functional theory . . .

     

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