Rearrangement of imidazolidine to piperazine rings in the presence of dyiii “2279

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SUMMARY

    Oreiro-Martínez, P.; Deibe, A.M.G.; Nitrogen heterocycles are undoubtedly the most important structural motifs in medical chemistry and pharmaceuticals. When this hydrolysis takes place, it typically cleaves the imidazolidine ring to transform the ligand into an amine. [Zn3 (L11 )(OAc)2 ]: To a solution of pentaethylenehexamine (0.107 g, 0.461 mmol): To a solution of pentaethylenehexamine (0.107 g, 0.461 mmol) in absolute ethanol (12 mL), Zn(OAc)2 ·2H2 O (0.100 g) and an ethanolic (15 mL) solution of 5absolute ethanol (12 mL), Zn(OAc)2·2H2O . . .

     

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