Reshuffle bonds by ball milling: a mechanochemical protocol for charge-accelerated aza-claisen rearrangements

HIGHLIGHTS

  • who: Christian Schumacher and collaborators from the Institute of Organic Chemistry, RWTH Aachen University, Landoltweg, Aachen, Germany have published the article: Reshuffle Bonds by Ball Milling: A Mechanochemical Protocol for Charge-Accelerated Aza-Claisen Rearrangements, in the Journal: Molecules 2023, 807 of /2023/
  • what: For the investigation , the authors focused on the synthesis of u03b3,u03b4-unsaturated amide 3aa accessible by a -sigmatropic bond reorganization event between propionyl chloride (1a) and N-allylmorpholine (2a). The authors focused the preparation of startingofmaterial was or not reproducible.
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