HIGHLIGHTS
SUMMARY
Carbon monoxide is a harmful pollutant, especially indoors or inside vehicle cabins, and many efforts have been devoted to oxidize CO to CO2 at low temperatures. The signal of CO(g) can be mathematically subtracted to solely reveal the signal of adsorbed species by using a reference spectrum collected under identical reaction conditions over a matrix that does not adsorb CO, e_g, KBr or SiC. Several authors have proposed that CO could bound strongly to PtOx species and be unreactive, although the exact nature of the sites, e_g, single Pt cation or PtOx clusters . . .
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