Stabilization of glucosyl dioxolenium ions by “dual participation” of the 2,2-dimethyl-2-(ortho-nitrophenyl)acetyl (dmnpa) protection group for 1,2-cis-glucosylation

HIGHLIGHTS

  • who: Wouter A. Remmerswaal and collaborators from the Wouter ARemmerswaal, Leiden Institute of Chemistry, Leiden University, CC Leiden, The Netherlands have published the research work: Stabilization of Glucosyl Dioxolenium Ions by u201cDual Participationu201d of the 2,2-Dimethyl-2-(ortho-nitrophenyl)acetyl (DMNPA) Protection Group for 1,2-cis-Glucosylation, in the Journal: (JOURNAL) of June/24,/2022
  • what: The authors investigate the origin of the stereoselectivity induced by the group through systematic glycosylation reactions and infrared ion spectroscopy (IRIS) combined with techniques such as isotopic labeling of the anomeric center and isomer population analysis . . .

     

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