Structures of two diastereomeric aldol products from a new silicon-directed condensation

HIGHLIGHTS

  • who: Permanent link and colleagues from the This Article was downloaded from Harvard University's DASH repository, and is made available California Institute of Technology, Pasadena, California, USA have published the paper: Structures of Two Diastereomeric Aldol Products from a New Silicon-Directed Condensation, in the Journal: (JOURNAL)

SUMMARY

    The silicon-bridged nine-membered ring aldol products (I) and_(II) were formed in a new silicon-directed aldol condensation reaction (Myers H3 o~Si N,xCH3 ant/-Diastereomer (I) Of 3 xCH3 O----Si N syn-Diasteteomer CI7H25NO38i involves trigonal bipyramidal silicon with . . .

     

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