HIGHLIGHTS
SUMMARY
By the time the authors started the research, in the world literature, methods for the synthesis of sulfur-containing derivatives were described, focusing on C60 -fullerene, with the most attractive synthetic point of view being a method based on the thermal interaction of carbon clusters with diazo compounds. As a follow-up to the ongoing work in the group related to the selective functionalization of C60 -fullerene with diazo compounds, the authors studied the catalytic cycloaddition reaction of sulfur-containing diazoalkanes generated in situ by the oxidation of hydrazones of the corresponding ketosulfides with . . .
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