Synthesis and characterization of phosphinecarboxamide and phosphinecarbothioamide, and their complexation with palladium(ii) complex “2279

HIGHLIGHTS

  • who: Masumi Itazaki and colleagues from the Department of Chemistry, Graduate School of Science, Metropolitan University, Sumiyoshi-ku, Japan have published the research: Synthesis and Characterization of Phosphinecarboxamide and Phosphinecarbothioamide, and Their Complexation with Palladium(II) Complex "2279, in the Journal: Molecules 2022, 5564 of /2022/
  • what: The authors report the synthesis of isocyits thiocarbonyl analog (phosphinecarbothioamides) with the same transition-metal complex anate/isothiocyanate without using a transition-metal catalyst and the reactions of precursor.
  • how: This result is in contrast withThis the ingly theofhydrophosphination reaction of took 2-chlorophenylisothiocyanate took place . . .

     

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