HIGHLIGHTS
- who: Su-min Song from the (UNIVERSITY) have published the research work: Synthesis of cis-thiiranes as diastereoselective access to epoxide congeners via 4u03e0-electrocyclization of thiocarbonyl ylides, in the Journal: (JOURNAL)
- what: The authors report a general synthetic method for cis-diarylthiiranes through the stereospecific sulfurization of aldazine N-oxides.
SUMMARY
In contrast, synthetic studies on thiirane were rarely reported, and thus the useful sulfur-congener of oxirane has been difficult to access in a stereodefined form. In this research, a general stereoselective synthesis of cis-thiiranes is accomplished by . . .
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