Synthesis of i(iii)/s(vi) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds

HIGHLIGHTS

  • who: Li Li from the (UNIVERSITY) have published the research work: Synthesis of I(III)/S(VI) reagents and their reactivity in photochemical cycloaddition reactions with unsaturated bonds, in the Journal: (JOURNAL) of 25/Oct/2022
  • what: The authors report the synthesis of a class of hypervalent iodine reagents with a transferrable sulfoxonium group. The authors report a general method to Nature Communications | 13:6588 acyclic reagents (3c-3w) are relatively less stable compared to 3a and 3b.
  • how: These results indicated that two distinct reaction pathways were operative when aliphatic olefins and . . .

     

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