Synthesis of sulfoximines and sulfonimidamides using hypervalent iodine mediated nh transfer

HIGHLIGHTS

SUMMARY

The sulfoximine and sulfonimidamide functional_groups are chemically stable azaanalogues of sulfones and sulfonamides, respectively. The use of O‐mesitylenesulfonylhydroxylamine (MSH) can achieve sulfonimidamides more straightforward, with broad functional_group compatibility. The the authors review divided substrate involvingofeither NH transfer to sulfox‐ 2016, (Bullisand Luisi)by reported thetype, preparation NH sulfoximines from sulides or NH/O transfer to sulfides. The reaction could be and run sulfonimidamides more straightforward, broadtoluene functional_group compatibility. TheThe assessment combination has been applied more broadly in processes involving N‐transfer that may of the functional_group tolerance through the reaction scope and through . . .

 



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