HIGHLIGHTS
SUMMARY
The environmentally prevalent oxidation state of iron is governed by the redox environment (e_g, ). Such energetic couplings are rarely direct in biochemistry and often mediated by cofactor or membrane potential-based processes, and their redox potentials can be highly variable (e_g, ). Given iron`s environmental ubiquity and importance in contemporary biochemistry, it is also widely believed that iron catalysis may have been important for life`s emergence (e_g, ). Such reactions may produce to millions distincthundreds product types (e_g, ). type reactions, among others.hundreds Such reactions may of produce to millions of Complex chemicaltypes reaction . . .
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