HIGHLIGHTS
- who: Grettel Valle Bourrouet from the School of Chemistry, University of Costa Rica, COSTA RICA have published the article: The Transition-State Carbonyl Stretching Frequency in Ester Hydrolysis, in the Journal: (JOURNAL)
SUMMARY
The conversion of reactant molecules into transition-state (TS) complexes involves changes in their inertial features (translation and geometry) and the force constants associated with the different internal modes. Reactant-molecule force constants are in principle obtainable from the vibrational frequencies determined from spectroscopic measurements. The first two features are based on chemical intuition or isotopic labelling experiments, whereas the . . .
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