Total synthesis of ophiorrhine a, g and ophiorrhiside e featuring a bioinspired intramolecular diels-alder cycloaddition

HIGHLIGHTS

• who: Wei Cao et al. from the (UNIVERSITY) have published the Article: Total Synthesis of Ophiorrhineu2005A, G and Ophiorrhisideu2005E Featuring a Bioinspired Intramolecular Diels-Alder Cycloaddition, in the Journal: (JOURNAL)
• what: The authors report the first total synthesis of the monoterpene ophiorrhine via late stage bioinspired intramolecular Diels-Alder to form the intricate bridged and spirannic polycyclic system.
• how: In the context of the recent syntheses of monoterpene indole alkaloid including cymosid by bioinspired oxidative couplings the authors proposed to access ophiorrhine A through a bioinspired Diels-Alder cycloaddition from ophiorrhiside E (6 . . .
  

   

  

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