Trans-dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(iii) tetrafluoridoborate

HIGHLIGHTS

  • who: Experimental et al. from the Laboratoire have published the research work: trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate, in the Journal: (JOURNAL)

SUMMARY

    In the title manganese(III) complex, BF4 or trans-[MnCl2(cyclam)]BF4 (cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane), the MnIII ions occupy the center of a distorted octahedron coordinated by all four ligand nitrogen donors in the macrobicyclic cavity and two chloride ions occupy the axial positions. Intramolecular hydrogen_bonding involving the coordinated chloride ions and the hydrogen atoms of the cyclam . . .

     

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