Understanding acid lability of cysteine protecting groups

HIGHLIGHTS

• who: Iván Ramos-Tomillero and colleagues from the Institute for Research in Biomedicine (IRB Barcelona), Baldiri Reixac, Barcelona, SpainDepartment of Organic Chemistry, University of Barcelona, Martí i Franqués, have published the Article: Understanding Acid Lability of Cysteine Protecting Groups, in the Journal: Molecules 2013, 18, 5155-5162 of 16/02/2013
• what: The authors propose diphenylmethyl (Dpm) as a promising protecting group on the basis of its intermediate relative carbocation stability.
• how: This measure of stability was expressed by the total electronic energy difference (ΔE) between the carbocation (R+) and its . . .
  

   

  

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