X-h bond insertion promoted by heterogeneous dirhodium metal-organic cage with alkynes as safe carbene precursors

HIGHLIGHTS

• who: Lianfen Chen and colleagues from the Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing, China have published the paper: X-H Bond Insertion Promoted by Heterogeneous Dirhodium Metal-Organic Cage with Alkynes as Safe Carbene Precursors, in the Journal: Molecules 2023, 608 of /2023/
• what: We disclosed the transformations of the functionalized alkynes as carbene precursors under the catalysis of a metal-organic cage (MOC-Rh-1), which contains dirhodium clusters as both building blocks and active_sites.
• how: These results indicated that the heterogeneous MOC-Rh-1 catalyst was not as effective as . . .
  

   

  

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